Woolworths has increased the "Priority Delivery Hubs" from 41 to 150. List of stores
https://www.woolworths.com.au/shop/discover/community/news/is-your-store-a-priority-delivery-hub (some CBR stores listed in NSW).
These stores will be open to the public from 9am to 6pm (instead of 7am to 8pm of other stores) and won't be running the 7-8am weekday "Community Hour". (hours for WA stores slightly different)
Outside those hours, they'll be picking delivery orders.
Customers who have been approved for Priority Assistance will be able to place orders 6 days out, pending window availability.
Normal delivery customers (ie, not Priority Assistance approved) will be able to place orders 24 hours out, if there are any delivery slots remaining after the Priority Assistance orders are in.
They'll be monitoring orders and cancelling as needed to prevent people placing multiple orders and hogging all the slots.